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One electron oxidation and p-type delayed fluorescence of an aromatic amine studied by pulse radiolysis

โœ Scribed by R.V. Bensasson; J.K. Thomas

Publisher
Elsevier Science
Year
1969
Weight
620 KB
Volume
1
Category
Article
ISSN
0020-7055

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One-electron oxidation and demetalation
One-electron oxidation and demetalation of metalloporphyrins and chlorophyll a in dichloroethane solutions as studied by pulse radiolysis
โœ Haim Levanon; P. Neta ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 356 KB

Formation of cation radicals by pulse radiolysis of metalloporphyrins and chlorophyll a in 1,2dichIoroethane is reported. Demetalation of the metalloporphyrin by radiolytically produced HCl is also observed. Rate constants for demetalation of ZnTPP and Chl a are 1 .I X IO8 and = 3 X IO8 h!-' s-I\_ O