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One-dimensional structures of manganese(II), copper(II) and cobalt(II) coordination complexes [MnII(hfac)2L] (hfac=hexafluoroacetylacetonate anion; L=4,4-bipyridyl), [CuII(hfac)2L] (L=1,3-dipyridylpropane or 4,4-bipyridyl-N,N′-dioxide) and [CoII(hfac)2L] (L=4,4-bipyridyl-N,N′-dioxide)

✍ Scribed by M.John Plater; Mark R. St. J. Foreman; Alexander M.Z. Slawin


Book ID
108331910
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
112 KB
Volume
303
Category
Article
ISSN
0020-1693

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Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a