One Dimensional Coordination Polymer Constructed by 1,2-Bis(4-pyridinecarboxamido) ethane and Copper (II)
β Scribed by Ge Chun-Hua; Zhang Xiang-Dong; Guo Fang; Zhang Li-Tian; Yu Zhan; Guo Wen-Sheng; Liu Qi-Tao
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 296 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0256-7660
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π SIMILAR VOLUMES
## Abstract Two new coordination polymers of Pb^II^ complexes with bridging 4,4β²β[(1__E__)βethaneβ1,2βdiyl]bis[pyridine] (ebp), thiocyanato, and acetato ligands, [Pb(__ΞΌ__βSCN)~2~(__ΞΌ__βebp)~1.5~]~__n__~ (1) and {[Pb(__ΞΌ__βOAc)(__ΞΌ__βebp)](ClO~4~)}~__n__~ (2), were synthesized and characterized by
Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a