One-Dimensional Cobalt(II) and Zinc(II) Succinato Coordination Polymers with Nicotinamide: Synthesis, Structural, Spectroscopic, Fluorescent and Thermal Properties
β Scribed by Selcuk Demir; Veysel T. Yilmaz; Fatih Yilmaz; Orhan Buyukgungor
- Publisher
- Springer
- Year
- 2009
- Tongue
- English
- Weight
- 363 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1053-0495
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Three novel zinc coordination polymers (NH(4))(n)[Zn(Hida)Cl(2)](n) (1), [Zn(ida)(H(2)O)(2)](n) (2), [Zn(Hida)(2)](n)Β·4nH(2)O (3) (H(2)ida = iminodiacetic acid) and a monomeric complex [Zn(ida)(phen)(H(2)O)]Β·2H(2)O (4) (phen=1,10-phenanthroline) have been synthesized and characterized by X-ray diffr
The reactions of CoX 2 (X β«Ψβ¬ Br, Cl) with the planar, bidentate bridging ligand 2,1,3-benzothiadiazole (btd) in Me 2 CO led to the 2D coordination polymers +[CoBr 2 (btd)], n (1) and +[CoCl 2 (btd)], n (2). The structure of 1 was determined by singlecrystal X-ray crystallography. Complex 1 (C 6 H 4