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One-Bond 55Mn,13C Coupling Constants, a Correction

✍ Scribed by Daniel Rentsch; Wolfgang von Philipsborn; Vladimir Torocheshnikov

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
279 KB
Volume
34
Category
Article
ISSN
0749-1581

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✦ Synopsis

Previously published one-bond 55Mn,13C coupling constants have been recalculated using a revised lineshape Btting program, QUADR. The accuracy of the new data was confirmed by the simulation of quadrupole-broadened but resolved 13C and "F spectra of the model complexes K,[Co(CN),] and Li(AsF,j. The 55Mn,13C coupling constants lie in the range 128-189 Hz for Mn-CO bonds, 57-114 Hz for Mn-C(spz) bonds and 35-79 Hz for Mn--C(sp3) bonds.

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