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One- and two-photon induced fluorescence of Pacific Blue-labeled human serum albumin deposited on different core size silver colloids

✍ Scribed by Joanna Lukomska; Ignacy Gryczynski; Joanna Malicka; Slawomir Makowiec; Joseph R. Lakowicz; Zygmunt Gryczynski


Publisher
Wiley (John Wiley & Sons)
Year
2006
Tongue
English
Weight
397 KB
Volume
81
Category
Article
ISSN
0006-3525

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✦ Synopsis


Abstract

We studied one‐ and two‐photon induced fluorescence of Pacific Blue (PB)‐labeled human serum albumin (HSA) in the presence of different size silver colloids. The PB fluorescence emission intensity was observed with small (30–40 nm) and large (about 120 nm) colloids and compared with PB emission in absence of colloids. For the system with a small core size colloids we did not detect any fluorescence enhancement with one‐photon excitation and the enhancement observed with two‐photon excitation was about 2.5‐fold. In contrast, for large silver colloids we observed about a 2‐fold increase in PB fluorescence brightness for one‐photon excitation, and the enhancement with two‐photon excitation excided 13‐folds. Much stronger increases in brightness observed with two‐photon excitation, compared to one‐photon excitation, indicate a dominant role of enhanced local field in fluorescence enhancement on silver colloids in solutions. © 2005 Wiley Periodicals, Inc. Biopolymers 81: 249–255, 2006

This article was originally published online as an accepted preprint. The “Published Online” date corresponds to the preprint version. You can request a copy of the preprint by emailing the Biopolymers editorial office at [email protected]