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One- and two-electron chemistry in the reaction of nitrogen dioxide and nitrosyl halides with binuclear pyrophosphito complexes of platinum(II) and platinum(III)

โœ Scribed by Hedden, David; Roundhill, D. Max; Walkinshaw, Malcolm D.


Book ID
127251483
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
630 KB
Volume
24
Category
Article
ISSN
0020-1669

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The reaction of Pd(Me,en)Cl, (Me,en =N,N,iV',N'-tetramethylethylenediamine) with inosine and 5'-inosine monophosphate was studied as a function of chloride concentration and pH. Evidence for the formation of a 1:l complex with these nucleophiles is presented, and the kinetic data indicate that Pd(Me