𝔖 Bobbio Scriptorium
✦   LIBER   ✦

On vibrational bonding of IHI

✍ Scribed by J. Manz; R. Meyer; J. Römelt

Book ID
103021223
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
538 KB
Volume
96
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The VibrdtiOIlJl bond of IN1 is described in amlogy to the covalent bond of 13; by a Born-Oppenheimer-type sepJration of light ("'hydrogenic " g "electronic") and heavy ("iodines" s "protons") particle degrees of freedom. Competing potenttl energy decreases and hydropcn zero-point energy increases (for the IHI antisymmetric stretchins and bending modes) yield J minimum in the iodine symmetric stretching mode's potential energy which supports one bound vibrational 1Hl st3te.

📜 SIMILAR VOLUMES

A new possibility of chemical bonding: v
A new possibility of chemical bonding: vibrational stabilization of IHI
✍ J. Manz; R. Meyer; E. Pollak; J. Römelt 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 335 KB

Rccclved 8 September 1982 mhc IHI system has rour vlbntlonally bonded coUinur bound states They me located in the saddle point regon of a minimum-free potenti cncr~ surface.

Effect of hydrogen bonding on the vibrat
Effect of hydrogen bonding on the vibrational dephasing time in glycerol
✍ R. Dorsinville; W.M. Franklin; N. Ockman; R.R. Alfano 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 230 KB

The nbratlonal dephasmg of the methyl CH2 symmclnc stretch made III glycerol was duectly measured over an extendcd tcmpersture range usmg plmsecond cohercnr Raman pump and probe spectroscopy. The dephlsing time was found to mcrcasc dramatically a~ the tcmpcralure oi the supercooled hqmd ws lowered.