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On triplet exciton trapping in 1,4-dibromonaphthalene

✍ Scribed by J.M.J. Vankan; W.S. Veeman


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
498 KB
Volume
89
Category
Article
ISSN
0009-2614

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✦ Synopsis


Rcmvrd 10 I-cbruar} 1982; III I-ial form 16 hfarctr 1982 QUIZ the study of trlplct ~WIOP trapping in l.~dibromanaphChalcnc ir appcvs that several opuully ,~ccssible ewI tons cm cwt wrh c'wwt~on cncrgrs wlhm 1 cm-' and LfcUmes dlffcrmg by oh o orders of magnitude Furthermore usp-lk S'UWS cust ==2 cm-' below the CVZIIO~ band. D&~yrti fluorcsccnce -1~~s from anmhdatioo bctwcen an ewiton .tnd the wry slullou tq4ikc stile


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The ESR spectrum of linear triplet e&tons in single crystals of 1 $dibromonaphthaIene (DBN) was studied ig the temperature range berween 2Β°K and room temperature. The exciton migration maintains its one-dimensional character up to 300Β°K. The ESR hnewidth is strongly temperature dependent. This fact

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We report mcasuriincnts on spin-lattjce relaxation (SLR) of linear triplet excitons in I,4 dibromonaphthalcne .', (1.4 D?N) sin& crystals at liquid ~~,eliktemperatures and at room temperature. SLR was found to be temperature dcptidcnt but isotropkrvith respect 'to the T;;ternal magnetic field.