On the zero-phonon structure of single-crystal [Ru(bpy)3](PF6)2
โ Scribed by H Yersin; G Hensler; E Gallhuber
- Book ID
- 108323925
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 848 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0020-1693
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๐ SIMILAR VOLUMES
Highly resolved emission and absorption spectra of [ Os(bpy),] \*+ doped into single-crystal [ Ru(bpy),](C104)2, are reported. , Our investigations, at low temperatures (2 < Tg 50 K) and high magnetic fields (09 H< 6 T), lead to the following results: The three lowest excited states of [ Os( bpy)
Polarized absorption spectra of neat single-crystal [ Ru(bpy)J(PF& at 300 and 5 K are presented. The spectra show pronounced vibronic structure and it is possible to assign the vibrations to known Raman frequencies. Furthermore, the different electronic states corresponding to the vibronic transitio
Zeeman measurements made near 178 15 cm-' at 4.2 and 1.4 K on a Ru( bpy),( PF6)Z single crystal, in both absorption and luminescence, are presented. Most significantly, no effect is seen with B 11 c, but substantial shifts are seen with E I c. These measurements are in direct conflict with the inter