Ab initio calculations on twenty van der Waals dimers of small polar molecules at the experimentally observed intermolecular separation R, using Hartree-Fock molecular moments, show that the minima in the electroslatic mteraction expanded up to R-" converges to angular structures which are close to
On the van der waals energy of two half-spaces at small separations
โ Scribed by R.G. Barrera; E. Gerlach
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 181 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
It is shown that the introduction of a cut-off wavenumber corresponding to electron-hole excitations leads to a 10% reduction of the Lifshitz van der Waals attraction of low density metallichalf-spaces at small separations.
In order to explain experiments on the adhesion of solid particles in terms of van der Waals forces, the Lifshitz formula [I ] has been assumed to be valid for extremely small separations [2] (about 4 A). In this range; however, the lattice structure and the overlap width d U(d) KC 0)
๐ SIMILAR VOLUMES
In the above paper, we suggested that the observed asymmetric Z-V curves obtained with an STM on Au surfaces coated with hemiquinone monolayers represent molecular switching and rectification. Further studies have shown that films lacking these molecules sometimes exhibit Z-V curves with large disco
in previous papers, we presented an evaluation of the dispersion energy, using a double perturbation scheme and an "Epstein-Nesbet partition" of the individual molecular harn~ton~n~ The purpose of the present work is to check whether such dispersion energies, added to the SCF supermolecuie energies,