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On the Validity of the McConnell-I Model of Ferromagnetic Interactions: The [2.2]Paracyclophane Example

✍ Scribed by Deumal, Mercè; Novoa, Juan J.; Bearpark, Michael J.; Celani, Paolo; Olivucci, Massimo; Robb, Michael A.


Book ID
127024203
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
126 KB
Volume
102
Category
Article
ISSN
1089-5639

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A new ortho-lithiation of homochiral 4-N,N-diethylamido[2.2]paracyclophane 8 is the key to the production of a wide variety of 4,5-disubstituted homochiral ligands. c-Geminal bromination of 8 proceeds in high yields and the resulting bromide may be converted into a variety of 4,13-disubstituted liga