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On the Use of the Kinetic Method for the Determination of Proton Affinities by Fourier-transform Ion Cyclotron Resonance Mass Spectrometry

✍ Scribed by M. Decouzon; J.-F. Gal; M. Herreros; P.-C. Maria; J. Murrell; J. F. J. Todd

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
425 KB
Volume
10
Category
Article
ISSN
0951-4198

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✦ Synopsis

The use in Fourier-transform ion cyclotron resonance (FTICR) mass spectrometry of the collision-induced dissociation of proton-bound dimers, the kinetic method or Cooks's method, is tested. This method is compared with the proton-transfer equilibrium method. Good agreement between the two methods is observed. Advantages and limitations of the FTICR kinetic method are briefly discussed.

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