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On the use of the coulostatic method for the investigation of fast redox systems

✍ Scribed by E. Santos; T. Iwasita; W. Vielstich

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
618 KB
Volume
31
Category
Article
ISSN
0013-4686

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✦ Synopsis

An experimental analysis of the coulostatic method is presented. For the evaluation of the data, a fitting procedure is proposed, workin with the data in the Laplace frequency domain. Measurements on [Fe(CN&J3--/.-P and [Ru(NH,),]'+ '+ are presented and discussed The limit of the method, using a standard electronic device, is estimated to be in the order of ko = 1 cm s-I.

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## Abstract The dependence of the pitting potential (E~p~) of aluminum on chloride concentration, pH and the temperature of the solution was studied by the potentiodynamic method according to a statistical experimental design. The parameters of the statistical E~p~ model offered on the basis of Box