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On the use of the Born-Oppenheimer approximation in molecular problems

✍ Scribed by Andrew D Liehr

Book ID
107719134
Publisher
Elsevier Science
Year
1957
Tongue
English
Weight
605 KB
Volume
1
Category
Article
ISSN
0003-4916

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📜 SIMILAR VOLUMES

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A discussion is attempted of the validity of the Born-Oppenheimer approximation which is characterized as an asymptotic analysis leading to a semiclassical theory of molecular structure. It is suggested that there are inherent defects in the resulting semiclassical theory which will limit its utilit

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## Abstract A new derivation of the Born–Oppenheimer separation of electronic and nuclear motion is presented. The arguments used differ from those in earlier works in not being specially designed for molecules. Instead they aim at an intuitive understanding of the qualitative behavior of the low e

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Evidence demojhstsating an explicit nuclear coordinate dependence bf efectr&c matrix e&&s in the tran&ion \_ moment for phosphorescence to the ground state'vibration~ maRifofd has been found for substituted benzenes by an opticaliy detected microwave double resonance esperimen:. Theoretical expressi