๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

On the use of adsorption/desorption models to describe the forced periodic operation of catalytic reactors

โœ Scribed by David T. Lynch


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
337 KB
Volume
39
Category
Article
ISSN
0009-2509

No coin nor oath required. For personal study only.

โœฆ Synopsis


Abslrac

-A model, of the adso,rption/desorption type, is used to examine the behavior of a catalytic reaction system during forced cycling of the feed composition. It is shown that this model can predict the occurrence of resonant behavior. This rate enhanment during periodic operation is due to the system being forced to operate for part of each cycle in a region where multiple operating states could potentially exist. It is also shown that both sine and square wave forcing functions produce resonant behavior, with the forcing frequency determining which type of function will produce the maximum rate In two recent publications, Feimer et al. [I] and Jain et al. [2] examined the behavior of several kinetic models which were subjected to periodic variation of the feed stream reactant compositions. These models were of the adsorption/desorption (AD) type, namely, only kinetic steps involving adsorption, surface reaction and desorption are included in the mechanisms. From these studies, the authors concluded that AD models cannot be used to predict rate improvement during periodic operation. Thus, these authors have stated that AD models are not useful for explaining the many experimental observations of rate enhancement


๐Ÿ“œ SIMILAR VOLUMES


The use of periodic operation to improve
โœ A. Renken ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 570 KB

The influence of enforced periodic concentration variations on a continuous stirred tank reactor was studied theoretically. The unsteady-state-processing becomes advantageous under certain conditions. This can be shown for an irreversible consecutive-competing reaction. The yield and selectivitv of

On the use of ultraviolet resonance Rama
โœ P. Lagant; G. Vergoten; W. L. Peticolas ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB ๐Ÿ‘ 2 views

Normal modes analyses for different molecules with biological interest have been performed and checked via the calculation of resonance Raman intensities. For this purpose, molecular orbital calculations were used to determine bond order changes in the lowest-lying electronic transitions. These bond