A usual explanation of the "unusual mechanism of Lewis acidity
On the unusual mechanism of Lewis acidity manifestation in HZSM-5 zeolites
β Scribed by A.S. Medin; V.Yu. Borovkov; V.B. Kazansky; A.G. Pelmentschikov; G.M. Zhidomirov
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 405 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0144-2449
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π SIMILAR VOLUMES
The Lewis acidity of H-Y and HZSM-5 zeolites has been studied using lSN n.m.r, of adsorbed N20. It follows from lSN n.m.r, data that in H-Y zeolites a variety of Lewis acidic sites having different strengths of acidity is present. The number of the strongest Lewis sites is about 20-30 i~mole/g, i.e.
The acid sites in dealuminated HZSM-5 zeolite with crystal sizes down to the nanoscale were firstly characterized by the probe molecule trimethylphosphine (TMP). As evidenced by the combination of 31 P CP/MAS NMR, 27 Al MAS and 1 H β 27 Al CP/MAS NMR measurements, the BrΓΆnsted acid sites of both mic