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On the transition state for decarboxylation of β-keto acids and βγ-unsaturated acids

✍ Scribed by D.B. Bigley; J.C. Thurman

Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
148 KB
Volume
8
Category
Article
ISSN
0040-4039

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On the acid-catalyzed rearrangement of β
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The rearrangement of R,y-unsaturated ketones in acid has considerable potential for the synthesis of unusual bi-and tricyclic ring systems. In most examples described thus far, however, the double bond is present in the relatively strained cyclobutene ring.' We describe here a synthetically useful r