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On the time evolution of a born-adiabatic molecular state

✍ Scribed by Thomas J. Venanzi; Jerome M. Schulman

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
310 KB
Volume
95
Category
Article
ISSN
0009-2614

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✦ Synopsis

I'imc&pcnden~ pcrrurbation theory is applied to rhc problem of a "Born-adiabatic molecule" evolving in time when wbjcct 10 XI extcrn;ll timc-dcpendcnt puturbation. The treatmcnr uses double perturbation theory within the Dirac Yaria-~i~lrl~lt.~orlst;lnts mr~h~rd to correct both for nonadisbaticity and external perturbations. In the c~stl of resonance nonadi.dut ic cklrrcctions can become large while znvay from resonance the wuvcfunction can be approximated by a timedcpendent atli3luI ic w3cefimcIioil.

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