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On the thermal decomposition of COS

✍ Scribed by H. G. Schecker; H. Gg. Wagner

Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
404 KB
Volume
1
Category
Article
ISSN
0538-8066

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✦ Synopsis

The thermal dissociation of COS was investigated in shock waves with argon as carrier gas. The concentration was varied between 0.05 and 0.5% COS in argon, the total density from 2.5 x 10-5mole/cm3 to 2.5 x 10-3mole/cm3. Temperatures between 1500'K and 3100'K were applied.

For the reaction

the rate constant was found to be

in the low pressure range of the unimolecular reaction and in the high pressure range.

* This work was supported in part by the Office of Aerospace Research. We are grateful to

Professor Jost and Dr. Troe for many discussions.

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