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On the theory of transitions of F center electrons

โœ Scribed by H.J.G. Meyer


Publisher
Elsevier Science
Year
1954
Weight
273 KB
Volume
20
Category
Article
ISSN
0031-8914

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โœฆ Synopsis


conjecture an example using (1) has been treated. At the beginning of the process the electronic state was given by a wave-packet, the oscillator was assumed to be in the ground state. After half a period of the lattice oscillation, we find the electron being in part in bound states, which are connected with excited oscillator states. After one full period the initial state is essentially restored. This is of course a consequence of our simple model, in which only one oscillator is taken into account. Here further investigations are necessary. The following numerical example is given: If the binding energy of the electron is 0.1 eV, the transition probability for a 4-phonon process turns out to be about 10 It sec -1. This transition probability is at least by a factor of 104 greater than that given by the usual Born-Oppenheimer-approximation.


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