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On the theory of order-disorder transition and copolymer structure of DNA

✍ Scribed by Shneior Lifson; Giuseppe Allegra


Publisher
Wiley (John Wiley & Sons)
Year
1964
Tongue
English
Weight
180 KB
Volume
2
Category
Article
ISSN
0006-3525

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✦ Synopsis


The statistical mechanical theory of the helix-coil transition of DNA has been recently discussed by one of the authors, who considered an assembly of DNA molecules with a Markoff distribution of nucleotide sequences. The present communication improves upon the above mentioned theory by introducing approximate normalization factors for the unnormalized statistical weights of finding a given molecule of the assembly in a given microscopic state.


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Thermal characteristics of ethylene-vinylacetate (EVA) copolymers having vinylacetate contents ranging from 5 to 40 w/w % are studied by differential scanning calorimetry. It is first shown that EVA copolymers having a vinylacetate content lower than 30 w/w % obey the Flory and Burfield theories of