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On the theory of electron correlation in atoms and molecules: Relation between cluster expansion theory and the correlated wave functions method

✍ Scribed by Keith R. Roby

Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
437 KB
Volume
5
Category
Article
ISSN
0020-7608

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✦ Synopsis

Abstract

A relation between the cluster expansion theory of many electron wave functions and the correlated wave functions method is established. In this way, the theoretical basis of the method is elucidated and the approximations involved in its application become apparent. General forms of the correlated wave function, differing in certain important respects from that form usually assumed, are derived.

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