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On the Ternary Laves Phases {Sc,Ti}2M3Si (M: Cr, Mn, Fe, Co, Ni) with MgZn2-Type.

โœ Scribed by X. L. Yan; Xing-Qiu Chen; A. Grytsiv; V. T. Witusiewicz; P. Rogl; R. Podloucky; G. Giester

Publisher
John Wiley and Sons
Year
2007
Weight
13 KB
Volume
38
Category
Article
ISSN
0931-7597

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Zn11Rh18B8 and Zn10MRh18B8 with M = Sc,
Zn11Rh18B8 and Zn10MRh18B8 with M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Si, Ge, Sn โ€“ New Ternary and Quaternary Zinc Rhodium Borides
โœ U. Eibenstein; W. Jung ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 113 KB ๐Ÿ‘ 1 views

Zn 11 Rh 18 B 8 and Zn 10 MRh 18 B 8 with M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Al, Si, Ge and Sn are obtained by reaction of the elemental components in sealed tantalum tubes at 1500 K. They crystallize tetragonally with Z = 2 in the spacegroup P4/mbm with lattice constants a = 1771.2(2) pm, c = 2