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On the termination mechanism in the radical polymerization of methyl methacrylate at high conversions

✍ Scribed by A.I. Dyachkov; A.L. Yefimov; L.I. Yefimov; T.A. Bugrova; V.P. Zubov; A.F. Samarin; V.M. Artemichev; V.A. Kabanov


Book ID
118967759
Publisher
Elsevier Science
Year
1983
Weight
491 KB
Volume
25
Category
Article
ISSN
0032-3950

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Solution polymerization of methyl-methac
✍ P.-A. Fleury; Th. Meyer; A. Renken πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 515 KB

The kinetics of the solution polymerization of methyl-methacrylate is characterized by a strong increase of viscosity up to 6 orders of magnitude and auto-acceleration of the reaction rate due to the gel-effect. This can lead to thermal and kinetic reactor instabilities. The kinetics were determined