On the termination mechanism in the polymerization of vinyl monomers by an organo-iron complex
β Scribed by Yamamoto, Takakazu ;Yamamoto, Akio ;Ikeda, Sakuji
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 246 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
## Abstract **Summary:** The polymerizations of ethyl vinyl ether, __n__βbutyl vinyl ether and isobutyl vinyl ether were investigated with a series of pyridine bis(imine) complexes of iron(II) and cobalt(II) in the presence of methylaluminoxane. The cobalt catalysts showed much higher activity and
Ethyl 2-[ 1-(trimethylsilylperoxy)ethyl]propenoate 1, ethyl 2-[ 1-(dimethylvinylsilylperoxy)ethyllpropenoate 2, ethyl 2-[ 1-( l-(2-ethoxycarbonyl-l-methyl-2-propenylperoxysilyl)-l-methylethylperoxy)ethyl]propenoate 3, and 2-phenyl-2-trimethylsilylperoxypropane 4 were synthesized and added to the fre