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On the tautomerism of the thymine anion in the solid state: A Raman and infrared study

✍ Scribed by Bernhard Lippert

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
971 KB
Volume
9
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Solid state infrared and Raman spectra of thymine, thymine monohydrate, three types of chloro(thyminato‐N1)ethylenediamineplatinum(II) complexes and three types of potassium thyminate (trihydrate, monohydrate, anhydrous compound) are reported and compared. The effects of hydrogen bonding, intermolecular coupling, crystal symmetry and tautomerism are discussed. For the anhydrous potassium thyminate a tautomeric structure, different from that found in the tri‐ and monohydrate, is postulated.

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