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On the structure and reactivity of a stabilized phosphorane: methyl (triphenylphosphoranylidene) acetate

✍ Scribed by Kayser, Margaret H.; Hooper, Donald L.


Book ID
118750738
Publisher
NRC Research Press
Year
1990
Tongue
French
Weight
314 KB
Volume
68
Category
Article
ISSN
0008-4042

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## Abstract The structure and reactivity of the cysteine methyl ester radical cation, CysOMe^.+^, have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe^.+^ undergoes rapid ion–molecule reactions with dimethyl disulfide, allyl