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On the structure and properties of [O2]+ [Mn2F9]− and [O2]22+ [Ti7F30]2−

✍ Scribed by Bernd G. Müller

Book ID
104150845
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
49 KB
Volume
16
Category
Article
ISSN
0022-1139

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A new copper aluminum silicate CuAl 2 Si 2 O 7 (F,OH) 2 (cualsite) was synthesized hydrothermally from SiO 2 and Al 2 O 3 in a mineralizing solution 1 3 Na 3 AlF 6 ؉ 4 9 Al(NO 3 ) 3 ؉ 1 9 Cu(NO 3 ) 2 ؉ 27.8H 2 O at 600°C and 150 MPa. Cualsite grew epitaxially on the pinacoidal plane of the topaz si