On the steric course of addition of 1-lithio- and 1-magnesio-2-pivaloyl-1,2,3,4-tetrahydroisoquinoline to aldehydes and ketones. An x-ray crystal structure determination of the organomagnesium reagent
β Scribed by Dieter Seebach; Jesper Hansen; Paul Seiler; Jack M. Gromek
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 834 KB
- Volume
- 285
- Category
- Article
- ISSN
- 0022-328X
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## Abstract **Summary:** The crystal structure of syndiotactic 3,4βpoly(2βmethylβ1,3βbutadiene) has been determined by the joint use of molecular mechanics and Xβray diffraction. Molecular mechanics calculations have been performed both on the isolated chain and on the crystal by the use of various
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