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On the Stereochemistry of β-Elimination of β-Silyl Azides.

✍ Scribed by Laurent Chabaud; Yannick Landais

Book ID
101955426
Publisher
John Wiley and Sons
Year
2003
Weight
138 KB
Volume
34
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

On the stereochemistry of β-elimination
On the stereochemistry of β-elimination of β-silyl azides
✍ Laurent Chabaud; Yannick Landais 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 201 KB

Fluoride-mediated elimination of syn and anti b-silyl azides was shown to afford the corresponding (Z)-and (E)-olefins, respectively, demonstrating that b-elimination of b-silyl azides is stereospecifically anti.