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On the stability of cubic phosphorus, P8

✍ Scribed by Trinquier, Georges; Daudey, Jean Pierre; Komiha, Najia


Book ID
126023809
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
394 KB
Volume
107
Category
Article
ISSN
0002-7863

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## Abstract The thermodynamic stabilities of P~2~, P~4~, and three P~8~ cage structure were investigated through high‐precision CBS‐Q calculations. The CBS‐Q values for the bond energy of P~2~ (Ξ”E~o~: +115.7 kcal mol^βˆ’1^) and the formation of P~4~ from P~2~ (Ξ” E~o~:‐56.6 kcal mol^βˆ’1^) were in excel