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On the spin states of μ-oxo bridged oxomolybdenum(V) dimers. A conformational analysis by the angular overlap method

✍ Scribed by Mikotaj F. Rudolf; Bogusława Jeżowska-Trzebiatowska


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
331 KB
Volume
51
Category
Article
ISSN
0009-2614

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✦ Synopsis


The angular overlap model has been applied for the fist time in a confonnational study of ground state properties of coordination compounds. The existence of several triplet ground states resulting from continuous rotations about the MO-O-MO axis has been demonstrated for oxygen-bridged oxomolybdenum(V) dimers.