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On the spectral intensities of vibrational transitions in polyatomic molecules: role of electrical and mechanical anharmonicities

โœ Scribed by Subrata Banik, M. Durga Prasad


Book ID
120750183
Publisher
Springer
Year
2012
Tongue
English
Weight
262 KB
Volume
131
Category
Article
ISSN
1432-2234

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Intensities of Transitions in Non-Totall
โœ W.L. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 125 KB

The effect of the noncorrespondence of normal coordinates on the Franck-Condon factors governing the appearance of non-totally symmetric vibrations in electronic spectra is examined. In a two-dimensional symmetry species containing vibrations 1 and 2, transitions such as 1 1 0 2 1 0 , 1 1 0 2 3 0 ,