On the Specific Reactivity of Chlorins Toward an Electrophilic Attack on the Methene Bridges
โ Scribed by Pullman, Albert E.
- Book ID
- 124091148
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 267 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
In chlorinated ethylenes, the chlorine substitution exerts, by its electron withdrawal effect, a stabilization of the molecule which increases with the number auf chlorine residues. All chlorinated ethylenes are metabolically transformed, in a first step reaction, to epoxides which may rearrange to
The structure and reactivity of various bis-allylpalladium complexes occurring as catalytic intermediates in important synthetic transformations have been studied by applying density functional theory at the B3PW91(DZ P) level. It was found that h 1 ,h 3 coordinated bis-allylpalladium complexes are