Basis set expansion and correlation effects on computed lithium cation affinities have been evaluated for the oxygen and nitrogen bases CH30H, H&O, CO, CH3NH2, CH2NH, and HCN. The presence of diffuse functions on nonhydrogen atoms is found to be the most important single enhancement of double-and tr
On the sodium and lithium ion affinities of some α-amino acids
✍ Scribed by Gustav Bojesen; Torben Breindahl; Ulla N. Andersen
- Publisher
- John Wiley and Sons
- Year
- 1993
- Tongue
- English
- Weight
- 470 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
✦ Synopsis
The decomposition of 59 different cluster ions (generated by fast atom bombardment) consisting of two different amino acids and a sodium ion was analysed. The only fragment ions of significant abundance could be assigned to sodium ion-bound amino acids. Assuming that the most abundant ion in the fragment ion spectrum corresponds to the amino acid with the highest sodium ion affinity (SZA), the 20 common a-amino acids could be ordered with increasing sodium ion affinity as follows:
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