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On the sodium and lithium ion affinities of some α-amino acids

✍ Scribed by Gustav Bojesen; Torben Breindahl; Ulla N. Andersen


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
470 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis


The decomposition of 59 different cluster ions (generated by fast atom bombardment) consisting of two different amino acids and a sodium ion was analysed. The only fragment ions of significant abundance could be assigned to sodium ion-bound amino acids. Assuming that the most abundant ion in the fragment ion spectrum corresponds to the amino acid with the highest sodium ion affinity (SZA), the 20 common a-amino acids could be ordered with increasing sodium ion affinity as follows:


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