On the selectivity of stannylene-mediated alkylation and esterification of methyl 4,6-O-benzylidene α-d-glucopyranoside
✍ Scribed by David J. Jenkins; Barry V.L. Potter
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 350 KB
- Volume
- 265
- Category
- Article
- ISSN
- 0008-6215
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The secondary hydroxyl groups in methyl 4,6-0-benzylidene-/3-Dglucopyranoside (1) show i, towards various reagents, little selectivity in partial etherification and esterification reactions, compared to those in the corresponding cr-D-glucopyranoside derivative. Most of the selective benzylatiorG,
As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy