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On the selective elimination of intramolecular vibrational redistribution using strong resonant laser fields

✍ Scribed by Shaul Mukamel; Kaiyu Shan


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
382 KB
Volume
117
Category
Article
ISSN
0009-2614

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✦ Synopsis


A method is proposed Tor the sclafive elimination of in~ramolccular wbralional redwribunon (IVR) in polyalomic molecules by using a strong resonant laser excitation. When the Rabi frequency is larger than the Irquenq spread of an isolated group of molecular eigenstale IVR prw se totally suppressed. and the molecule simply oscdlales beluecn the ground stale and Lhe doorway skle The melhoL may have direct implkahons on laser-s.&c~ive chetistry.