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On the rotational spectra of endohedral atoms at fullerenes: the off-centre case

✍ Scribed by J. Hernández-Rojas; J. Bretón; J.M. Gomez Llorente

Book ID: 103031971
Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 545 KB
Volume: 237
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00244-x

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✦ Synopsis

A simple Hamiltonian describing the rotational dynamics of endohedral off-center atoms at fullerenes is reported. Using this Hamiltonian rotational spectra for Li + @C60 are calculated and the effect of the angular dependence of the atom-cage potential energy on such spectra is evaluated. Complexity, large density of transitions and the appearance of rotational oscillations and librational bands are the main features of the calculated spectra.

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