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On the rotation-vibration energy levels of a molecule. Perturbation approach to the semirigid model

✍ Scribed by J. Konarski


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
659 KB
Volume
90
Category
Article
ISSN
0022-2852

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A perturbation approach to the evaluatio
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The conventional perturbation theory is employed to &lculate.the vibrational contribution to the hyperfme coupling constant of the NH: radical ion. The perturbing hamiltonian is constructed by expanding the electronic hamiltonian in poweis of the outaf\_pIane vibration normal coordinate. SCF MO wav