Isotopic effects observed m the mfrared spectra of CO adsorbed on the Cu(ll1) surface are shown to be compatible with a dlpolecouphng model which relates frequency shifts to the accompanying changes III infrared band mtenslty.
On the role of period-amplitude dependence in the study of inertial effects and dipole-dipole coupling
β Scribed by William Coffey
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 570 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
An exact analytical formula for the complex polartzability of two dipoles constrained to rotate in two dimensions under the influence of their mutual dipole-dipole coupling is derived subject to the condition that the motion is lightly damped and that non-linear effects are weak. The inclusion of non-hnear effects due to the cosine potential of dtpole-dipole interaction even in first approximation
indicates that the natural frequency of oscillation of the angular velocity correlation functions depends on their amplitude and thus on the temperature.
The frequency of maximum far-infrared power absorption is found to depend on temperature in accordance with an earlier finding of Marchesoni.
The Q factor of the system appears to decrease with temperature in the same way as the natural frequency, but the bandwidth is relatively unaffected.
π SIMILAR VOLUMES
Hole mobilities were measured in a series of triphenylamine (TPA) molecules with different dipole moments doped into apolar and highly polar poly(styrene)s. The results are described by a formalism based on disorder, due to Bassler and coworkers. The formalism is premised on the assumption that char