Ultraviofet photoekction spectra from Rh~(C0)16 and from CO adsorbed on a Pd(l11) single crystal surfzce evhtblt cIose slmllarities which become further evident from a comparison of vibrational and thermal properties. These results demonstrate the localized character of the chemisorption bond and ju
On the role of d electrons in chemisorption and catalysis on transition metal surfaces
β Scribed by Carl F. Melius
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 396 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The possibility of correlated jumps in hydrogen self-diffusion on the Ni (00 I ) surface has been studied numerically at T= 2 50 K. It is found that excitations of electron-hole pairs among the conduction electrons are the dominating mechanism for energy dissipation in the present situation. Correla
A simple application of a readily available quantum chemistry program (AMPAC) permits an illuminating presentation of the role of vibrational modes in electronic transitions. A direct comparison of modal surfaces for different electronic states of the same molecule can be made by using a perspective