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On the role of core repulsion in the prediction of the energy levels of π-conformers

✍ Scribed by G. Re; F. Momicchioli; A. Rastelli


Publisher
Springer
Year
1972
Tongue
English
Weight
583 KB
Volume
23
Category
Article
ISSN
1432-2234

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A weak fluorescence was observed from benzophenone at 25650 cm+ with a quantum yield of ==lO-' at 5°K. With the assumption that \* n,r\* -3 n,r\* intersystem crossing is more efficient than r n,~\* + 3 n,~\*, the temperature dependence of the quantum yield sets the 3n,n\* level <, 50 cm-' above the