On the role of Brønsted acidity in the oxidation of benzene to phenol by nitrous oxide
✍ Scribed by V.I. Sobolev; K.A. Dubkov; E.A. Paukshtis; L.V. Pirutko; M.A. Rodkin; A.S. Kharitonov; G.I. Panov
- Book ID
- 103964458
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 392 KB
- Volume
- 141
- Category
- Article
- ISSN
- 0926-860X
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📜 SIMILAR VOLUMES
## Abstract α‐Pinene oxide (2) is a very reactive substrate which isomerizes rapidly under the influence of acid catalysts. A large number of products can be formed from a single intermediate. Selectivity to the industrially important campholenic aldehyde can be achieved with metal‐halogen compound
Molybdenum complexes / Peroxo complexes / Catalysis / Olefin epoxidation / Proton transfer NMR studies of the reaction of complexes of the type (L-L ) M O O ( O ~) ~ (L-L = bidentate ligand) with strong Brensted and Lewis acids prove that protons are transferred preferentially to an q2-peroxo and n