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On the role of bimolecular reactions in chemical activation systems

โœ Scribed by Olzmann, M.

Book ID
119943727
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
131 KB
Volume
4
Category
Article
ISSN
1463-9076

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A new treatment of steric effects in activated bimolecular reactions is presented. It is based on a development of the angle-dependent line-of-centres (ADLOC) model and treats the case where the critical surface dividing reagents and products is non-spherical. It is argued that it is the energy asso