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On the ring-contraction of 1,4-dithiins to 1,3-dithiole derivatives

✍ Scribed by Raquel Andreu; Javier Garı́n; Jesús Orduna; José M Royo

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
62 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

The effect of different factors (pK a of the base, nature of the counterion and dissociation of the ion pairs) on the course of the base-induced rearrangement of 1,4-dithiins to 1,3-dithiole derivatives is discussed. Ab initio calculations account for the driving force of these isomerisations.

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