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On the reversibility of homolytic aromatic substitution II. The phenylation of o-dichlorobenzene

โœ Scribed by Roberto Henriquez; Derek C. Nonhebel

Book ID
104224431
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
88 KB
Volume
16
Category
Article
ISSN
0040-4039

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The benzyl radical addition to ethylene is a reversible process at 9OOC'. Considering that the addition of a free radical to benzene has been estimated2 to be less exothermic of ca. 11 Kcal/mole than the corresponding addition of a benzyl radical to ethylene, the addition of a benzyl radical to an a