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On the relative stabilities of Si6H6 isomers

✍ Scribed by Zdeněk Slanina

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
312 KB
Volume
161
Category
Article
ISSN
0009-2614

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✦ Synopsis

Si6H6( g) is treated as an equilibrium mixture of three isomers using recent advanced ab initio data. It is shown that equimolarity of hexasilaprismane with hexasilabenzene (lying 41 kJ/mol higher in potential energy) is reached at a temperature of 340 K while the third isomer (hexasila-Dewar benzene) is present to a negligible degree.

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