On the relationship between unimolecular lifetime and relative translational energy distributions
โ Scribed by William L. Hase
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 228 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Relative translational energies are computed for H-C-C-C1 decomposition using classical trajectories. It is found that excited molecules with non-RRKM lifetime distributions dissociate to products with RRKM translational energy distributions. This result suggests that statistical relative translational energy distributions do not necessarily imply complete intramolecular vibrational energy redistribution.
๐ SIMILAR VOLUMES
Comparison of fracture energy and shear index in a series of dynamic tear (DT) tests of quench and tempered carbon and low alloy steels and their weldments has shown that the shear index is related to the fracture energy of the specimens over a wide range of temperatures, compositions and weldment l
In a previous paper [J. R. Matthews, On the relationship between shear index and energy in dynamic tear specimens. Engng Fracture Mech. 39, 131-140 (1991)], a relationship was shown to exist between the fracture energy and shear index in a series of dynamic tear (DT) tests of quench and tempered car