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On the relationship between unimolecular lifetime and relative translational energy distributions

โœ Scribed by William L. Hase


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
228 KB
Volume
67
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Relative translational energies are computed for H-C-C-C1 decomposition using classical trajectories. It is found that excited molecules with non-RRKM lifetime distributions dissociate to products with RRKM translational energy distributions. This result suggests that statistical relative translational energy distributions do not necessarily imply complete intramolecular vibrational energy redistribution.


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