✦ LIBER ✦

On the relationship between fluorescence and molecular geometry solvent-assisted formation of luminescent intramolecular exciplexes from anthronyl-substituted anthracenes

✍ Scribed by Hans-Dieter Becker; Kjell Sandros

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 322 KB
Volume: 53
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)85385-8

No coin nor oath required. For personal study only.

✦ Synopsis

The fluorescence efficiency of 1',2'-dihydro+.pirc[anthracene-9(lOH).3'-[3H]

benz[de] anthracenl-lO-one in 10 sokents of varying dieIectric constant has been iavestigated. The observed exciplex Iuminescence is attributed to a solventassisted intramolecular charge-transfer interaction between the ground-state anthrone and excited-state anthracene moieties_ The geometry of the exciplex is susested to resemble that of a u-r complex.

📜 SIMILAR VOLUMES

On the relationship between fluorescence

On the relationship between fluorescence and molecular geometry. Formation of a luminescent intramolecular anthracene-ethylene exciplex by electronic excitation of lepidopterene

✍ Hans-Dieter Becker; Kjell Sandros 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 500 KB

Electronic excitation of the bridged benzenoid hydrocarbon Iepidopterene @.) in the crysWine state and in soiution gives rise to an anomalous luminescence which is attributed to the radiative deactivation of an intramolecular anthraceneethylene exciplex E\*. The formation of E\* and the regeneration